• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1:2 Chromium complexes of the formula, <IMAGE> I in which R1 is hydrogen, chlorine, bromine, nitro (being meta to the first nitro group), C1-4alkyl or C1-4alkoxy, R2 is hydrogen or nitro, Y is <IMAGE> wherein R3 is hydrogen, chlorine, bromine, trifluoromethyl, C1-4alkyl or C1-4alkoxy, and R4 is hydrogen, chlorine, bromine, C1-4alkyl or C1-4alkoxy, and A is a <IMAGE> wherein the carbon atom marked with the * is bound to the azo radical, which complexes are in free acid or salt form, and mixtures thereof, are useful for dyeing and printing nitrogen-containing organic substrates, for example, natural and synthetic polyamides such as wool, silk and nylon, polyurethanes, polyolefins modified to contain basic groups and leather, for dyeing metals such as anodized aluminum and in printing lacquers and ball-point pen inks.
    公开号:SU1168098A3
    申请号:SU802980104
    申请日:1980-09-23
    公开日:1985-07-15
    发明作者:Доре Жакки
    申请人:Сандос Аг (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to the technology of finishing synthetic materials. fishing, in particular, to the method of dyeing and printing natural, synthetic polyamides or natural leather with a composition based on a metal complex azo-paint l.
    The known method of dyeing and printing natural, synthetic polyamides or natzfalny skin by treating the substrate with a dyeing solution or printing paste based on a metal complex azo dye asymmetric 1: 2. Co-complex mono-dyes formulas
    HE
    OoN
    Taking into account the material in a ratio of up to 1:16 1. However, the known method is characterized by insufficient light resistance of 1–5–6 points.
    The aim of the invention is to improve the lightfastness of the color and improve the purity of its color.
    This goal is achieved in that according to the method of dyeing or printing natural synthetic polyamides or natural leather by treating the substrate with a dye solution or printing paste based on a metal complex azo dye, the latter use the chromium azo dye of the general formula
    where R is hydrogen, chlorine, bromine, nitro in the meta position to the existing nitro group, alkyl with 1-4 carbon atoms or alkoxy with 1-4 carbon atoms /
    R hydrogen or nitro / residue of the formula
    Have
    25
    R is hydrogen, chlorine, bromine, trifluoromethyl, alkyl or alkoxy group with 1-4 carbon atoms {
    four
    hydrogen, chlorine, bromine, alkyl- or alkoxy group with 1-4 carbon atoms; divalent residue
    40
    45
    where the asterisk indicates the carbon atom bound to the carbon group, or its salt, in an amount of 0.01-6.0 wt.% on the substrate in the dye solution or 0.18, 0 wt.% in the printing paste. The sulfo group contained in the chromium complexes of formula (1) is in the form of a free acid or preferably in salt form. As a player
     J
    sulfo group of the cation can use any non-chromophore cation. 3 for example, an alkali metal ion, an unsubstituted or substituted ammonium ion: lithium, sodium, potassium, ammonium MONO-, DI-, tri- and tetramethylammonium, tr1 ethylammonium and mono-, di- and triethanolammonium. Preferred cations are alkali metal ions and unsubstituted ammonium ions, sodium is particularly preferred. Amines can also be used for neutralization, the presence of which in the form of ammonium ion reduces the water solubility of the (1: 2) chromium complexes according to the invention so that they can be dissolved exclusively in organic solvents. Such amines are N-ethyl, N-hexylamine, cyclohexylamine, N, N-dicyclohexyl amine or cyclic amines, for example morpholine. The negative charge of the complex anion of the cation is used as a compensation for the hydrogen or one of the indicated sulfo groups in the salt form of the cations. The cation of the sulfo group and the cation of the complex anion may be the same or different. (1: 2) -chromic complexes of the formula (1). in which the complex anio is compensated by hydrogen, they can be hardly soluble in water. Asymmetric (1: 2) -chromic complexes of formula (1), and mixtures of them are obtained by attaching an To (1: 1) -chromic complex from a compound of formula NH-y 1 -N- / 0 or mixtures of such compounds or from a compound of formula NHSZ 98. 4 or mixtures of such compounds, one or more metal-free compounds of formula (III), or, respectively, formula (II), Asymmetric (1: 2) -chromic complexes of formula (1) are prepared according to a known method, preferably starting from (1: 1) -chromic complex containing sulfo groups of monoazo compounds of formula (III) and the addition of thereto with no hold-sulfo compound of formula (II). The components of the reaction are used in approximately stoichiometric amounts. The interactions are carried out in an aqueous solution and / or in an organic solvent, for example, in a low molecular weight aliphatic alcohol such as ethanol, or in an amidocarboxylic acid, such as formamide or its alkyl derivatives, or in glycols such as ethylene glycol, di- or triethylene glycol, or their ethers. The reaction is carried out at a pH of 5-12, preferably at a pH of 6-9 and at temperatures before, and is completed after the conversion of the whole (1: 1) -chromic complex used. Then the (1: 2) -chromic complex is isolated in a known manner, for example, by salting out or weak acidification, and after washing with a saline solution, collected and dried. The compounds used as starting materials (1: 1) -chromic complexes can be obtained in a known manner, for example lead (1: 1) -chroming in an aqueous medium at pH 1-4, preferably at pH 2-3, and at temperatures up to 150 ° C, preferably at 100-140 ° C. Offered according to the invention (1: 2) -chromic complexes of the formula (1) and mixtures thereof are used in the form of alkali metal salts, or ammonium salts in organic amines, suitable for dyeing and printing (printing) of arganic nitrogen-containing substrates, in particular textile materials, which consist of natural or synthetic polyamides (wool, silk, nylon, perlon, helank), and also dyeing and printing (printing) of the skin.
    five
    Conventional methods can be used for dyeing and printing. When dyeing (1: 2) -chromite complexes of formula (1) are used in an amount that corresponds to the saturation limit of the substrate, dyeing is appropriately carried out in the presence of water. For printing (printing), the printing paste used contains up to 8% pure dye, along with water and conventional aids, the preferred content of pure dye is 0.01-6% based on the weight of the material to be painted. For liquid dye preparations in the form of stable concentrated solutions, water-soluble organic matter solvents are used, under known conditions, in a mixture with water, and conventional adjuvants such as urea can be added. These concentrated solutions are immediately mixed with water.
    Highly concentrated liquid storage dye compositions that are stable to 1FIs are also obtained by liquid-liquid extraction: a homogeneous or almost homogeneous dye solution consisting of water and a limited water-miscible solvent, such as organic acid amide, glycol ether or polyhydric alcohol (polyglycol), is obtained with known conditions with additional salt added, heated and after separation the dye is separated from the aqueous salt phase.
    The proposed (1: 2) -chromic complexes provide light-resistant waterproof coloring, which, moreover, is resistant to friction, carbonization, ironing, chlorination of wool, as well as acids and alkalis. I
     Dyes have high dyeability, due to their asymmetric nature, they uniformly dye polyamide fibers in a neutral medium.
    In addition, the compounds of formula (1) (which are soluble in water on the basis of the cations contained in them) differ in printing very good solubility: well applied printing pastes are obtained on all grades of polyamides.
    8098o
    whose good stability is manifested primarily in an acidic environment.
    Example 1. Paste from 106.4 ma.ch. (ob.ch.) (1: 1) -chromic polyamine monoazo compound obtained from 1-amino-2-hydroxynaphthalene-4-sulfonic acid and 2-hydroxy naphthalene, and monoazo compound obtained by acid combination of a diazotized 2-amino-4,6 -dinitro-1-hydroxybenzene with 2-phenylaminonaphthalene, stirred in an amount of water such that the volume was 1200 parts by volume, and an additional 60 parts by weight added to the water. (ob.ch.) ethylene glycol. With a solution of caustic soda with a concentration of 30%, the pH is adjusted to 6.0-7.0 and the pH is maintained at this J value up to the end of the reaction, and in general, approximately 50 parts by weight are taken for this purpose. (ob.ch.) 30% aqueous solution of caustic soda. Stir at 90 ° C until the starting materials (1: 1) are a chromium complex and an additive. This compound is no longer detected or is only detected as traces using gas chromatography (this transformation takes approximately 2-3 hours).
    After cooling to 50-60 ° C, 180 mas were added. (ob.ch.) sodium chloride, stirred for 30 minutes at 50-60 ° C, then filtered and dried at. The dye thus obtained, which in the form of the free acid corresponds to the formula A
     0, N
    H
    It is obtained in the form of sodium salt, it dissolves very well in water and dyes natural and synthetic polyamide fibers (wool, nylon, helanka or perlon) in greenish-dark gray to black shades (depending on the amount of dye used). Coloring has high water resistance and light resistance. Examples 2-25. According to the example, 1 other asymmetric 1: 2 chromic complexes are obtained, for which table 1 shows the original compounds: as a (1: 1) -chromium complex (containing sulfo groups) and as a metal-free additive. . It is also possible to proceed from the (1: 1) -chromic complex, to which a monoazo compound containing sulfo groups is attached. The color obtained as a result of the use of the (1: 2) -chromic complex (in the form of sodium salt) on natural and synthetic polyamides has high stability, water resistance and light resistance, shades are black in all cases (slightly greenish) or greenish. gray depending on the selected amount of dye. The dyes of examples 1-25, depending on the reaction conditions (conversion) and release, are obtained instead of the sodium salt, also in free acid form or in another salt form, for example, with one of these cations. Example 26. 150 mach. (ob.ch.) dry dye of Example 1 is dissolved in 150 parts by weight. (vol., diethylene glycol monobutyl ether and 600 parts by weight (parts by volume) of water. The salt content is set equal to 150 g / l and an almost homogeneous solution is obtained. This solution is heated to boiling, and two phases are obtained. The upper one that is colored in dark the color, the solvent dye phase and the lower, almost colorless, salt-containing, aqueous phase are separated from each other at a temperature just below the boiling point. Thus, the resulting dye solvent has a concentration of about 45% and is stable during storage. if instead polyethylene glycol (mol. 300), polypropylene glycol (mol. 3000) or dimethylbenzamide in the same amounts are used for ethylene glycol monobutyl ether. 8. 8 Similarly, the substances listed in the table are processed into storage stable liquid dye compositions .. Example 27. 0.1 parts by weight of the dye obtained in Example 1 is dissolved in 300 parts by weight of water and 0.2 parts more of ammonium sulfate is added. Then it is introduced into a bath with pre-moistened material (5 May . of wool gabardine or 5 ma. nylon-satin) and heated for 30 minutes at boiling point. The water which had evaporated during this boiling time is added and the coloring is completed within the next 30 minutes of boiling. Then the material is rinsed. After drying, a dark gray with a greenish tint is obtained with a very good color and water resistance. By the same method, the material is dyed with dyes according to examples 2-25 or with a range of two or more dyes according to examples 1-25 or with a composition according to example 26. The colors have high light resistance (6-7 points) and good water resistance. Example 28. Polyamide type (stuffed) printing paste of the following composition: 50 mach. dye according to example 1, 50 MA. urea 50 ma.ch. a recovery agent (e.g. thiodiethylene glycol) J 300 wt.h. water {500 math. thickeners (for example, on the basis of Johannisbrot kernmehl flour; 60 parts by weight of an acidic agent (for example ammonium tartrate); 60 parts by weight of thiourea. Printed (stuffed) textile material is steamed and decanted for 40 minutes at 102 ° C (saturated steam) , then cold rinse, then for 5 min at 60 ° C, wash with a diluted solution of commercial detergent and rinse again in the cold.Good-colored prints with very good electricity and water resistance are obtained, which are colored in dark gray with a greenish tinge. VC The four parts contain the dye according to examples 2-25 or a mixture of two or more dyes according to examples 1-25, and are applied in the same way. 9 Example 29. Skin dyeing 100 parts per sheep skin (Agneaux Stain NCR type) and 2 parts per dye of Example 1 were treated for 60 minutes in a dyeing drum in a dyeing solution of 800 parts of water at 55 ° C and 1.5 parts per hour of anionic emulsion of spermacetium A1aela, and with a slow addition of 10 May. hours, formic acid (85%) for 45 minutes on the skin nano t of koreitel. The painted material is then washed for 5 minutes with 100 mash. water at 25 ° C. After a normal finish and finish, a dark-green color with a green tint and a good leveling effect is obtained. Example 30. A comparison of the indices of light fastness of the coloration according to the proposed method and the prototype method is carried out. Compare the color of nylon 66 (Helanka), obtained using aeymmetrical (1: 2) -chromic complex of example 1, e by coloring by a dowel of example 22 (by prototype) for light resistance. The kraitel-PO of the prototype method is obtained from the same structural mono-label as proposed dye of Example 1, the difference is that in the prototype an asymmetric (1: 2) -balt complex is used
    Table 1 810. Dyeing is carried out according to the pattern of dyeing of helank-type yarns (with a thickness equalizing the coloring of the spruce, about 1/16 of the depth of the straightening type) and is carried out on the electrical outlet. The obtained samples (irradiation times 100 and 200 hours) are estimated by the actual scale (estimates 1–8). The results are presented in table. .2. The color obtained by the proposed dye for the whole unit is more natural than the color according to the prototype prototype. The coloration of natural leather obtained by using the proposed (1: 2) -Cr-complex according to example 1 and (1: 2) -Cp-comlex type according to the prototype is compared. The results are presented in table. 3. Apply the same type of staining techniques, weighing 100 hours, irradiated with light corresponding to the skin ridge. In the case of (a) the difference is 1/2 of the estimate (the estimate of the coloration of the proposed dye is closer to 6, the estimate of the prototype is closer to 5), in case of (b) the difference is more than 1/2 of the mark. As follows from the examples, the proposed method makes it possible to increase the resistance of the paint from 5-6 points to 6-7 points (on polyamides) and by 0.5 points on the skin.
    1-Amino-2-hydroxynaftapine-4-sulfoxyelot - 2-oxyaphthalene
    2-amino-1 -oxy-5-nitrobenzene-2-phennlaminonaphthalene
    2-amino-1-hydroxy-5-nitrobenzene -2- (g-chlorophenyl) -aminonaphthalene
    2-amino-4-chloro-1-hydroxy-5-nitrobenzene 2-phenylaminonaphthalene
    2-amino-4,6-dinitro-1-hydroxybenzene (3-chlorophenyl) -aminonaphthalene
    1-amino-2-hydroxy naphthalene-4-sulfonic acid 2-hydroxy naphthalene
    1-amino-2-hydroxy-6-nitronaphthalene-4-sulfonic acid - 2-hydroxy naphthalene
    ten
    eleven
    12
    1-amino-2-hydroxy-6-nitro13 naphthalene-4-sulfonic acid -2-oxnnaphthalene
    14
    1-amino-2-hydroxynaphthalene 15 -4-sulfonic acid-1-hydroxynaphthalene
    sixteen
    17
    18
    nineteen
    1-amino-2-hydroxynaphthalene-4-sulfonic acid -2-hydroxynaphthalene
    20
    21
    1-amino-2-hydroxy naphthalene-4-sulfonic acid; 2 hydroxy naphthalene
    2-Amino; -oxy 4-methyl-6-nitrobenzene 2-fekilaminonaphthalene
    2-Amino-1-hydroxy-6-methyl-4-nitrobenzene 2-feNi-Laminonaphthalia
    2-amino-1-hydroxy-4-methoxy-6-itrobenzene - -2-phenylaminonaphthapine
    2-Amino-4,6 dinitro-1-hydroxyebol-2-phenylaminonaphthalene
    2-Amino-4,6-dinitrot-1-hydroxybeneol-2- (3-chlorophenyl) -amino-naphthalene
    2-amino-4-chloro-1-oxyg5-nitrobenzene-2-phenylaminonaphthalene
    2-amino-4-chloro-1-hydroxy-5-nitrobenzene 2- (3-chlorophenyl) -aminonaphthalene
    2-Amino-1-hydroxy-5-nitrobenzene-2-phenylaminonaphthalene
    2-amino-1-hydroxy-4-methyl-6-nitrobenzene 2-phenylaminonaphthalene
    2-amino-4-chloro-1-hydroxy-5-nitrobenzene 2-phenylaminonaphthalene
    2-A Dano-4,6-dinitro-1-oxybenzole - 2-phenylaminonaphthalene
    2-Amino-4-chloro-1-hydroxy-5-nitrobenzene 2-Fensch1aminonaphthalene
    2-Amino-1-hydroxy-5-nitrobenzene-2-phenylaminonaphthalene
    2-amino-4-chloro-1-hydroxy-6-nitrobenzene 2-phenylaminonaphthalene
    2-Amino-4,6-dinitro-1-oxyben $ ol - 2- (4-chlorophenyl) -aminonaphthalene
    2-amino-6-chloro-1-hydroxy-4-nitrobenzene 2-phenylaminonaphthalene
    23
    24
    1-amino-2-hydroxynaphthalene-4-sulfonic acid - «-2- Oxymphthalene
    25
    2- (2, 4-dimethylphenyl) -aminonaphthalene
    2-amino-4,6-dinitro-1-hydroxybenzene 2- (4-methylphenyl) -amino-naphthalene
    2-amino-4,6-dinitro-1-hydroxybenzene 2- (4-methoxyphenyl) -aminonaphthalene
    2-amino-1-hydroxy-4-nitrobenzene 2-phenylaminonaphthalene
    权利要求:
    Claims (1)
    [1]
    METHOD FOR DYEING OR PRINTING NATURAL, SYNTHETIC POLYAMIDES OR NATURAL SKIN by treating the substrate with a dyeing solution or a printed paste based on a metal complex azo dye, characterized in that, in order to increase the color fastness of the dye, chromium-containing azo dichromide is used as a dye, with hydrogen of the general formula: , nitro groups in the meta position to the existing nitro group, alkyl with 1-4 carbon atoms or alkoxy group with 1-4 carbon atoms;
    R 2 is hydrogen or a nitro group, y is a residue of the formula
    R 3 is hydrogen, chlorine, bromine, trifluoromethyl, an alkyl or alkoxy group with 1-4 carbon atoms (
    R 4 is hydrogen, chloro, bromo, alkyl or alkoxy with 1-4 carbon atoms;
    A is a divalent residue of the formula "SU 1168098 where an asterisk indicates a carbon atom bound to> azo group or / its salt, in an amount of 0.0Ιό, May 0.% Per substrate in a dye solution: or 0.1-8.0 wt.% in printing paste
    类似技术:
    公开号 | 公开日 | 专利标题
    JP4624554B2|2011-02-02|Triphendioxazine dyes for organic substrate dyeing
    SU1168098A3|1985-07-15|Method of dueing or,printing natural,synthetic polyamides or natural leather
    DE2704364C2|1988-04-14|
    DE2636798C2|1984-07-12|Asymmetric 1: 2 chromium complex azo compounds, their preparation and use
    ES2806080T3|2021-02-16|Bisazo dyes and mixtures of these
    JPH08253698A|1996-10-01|Reactive dye mixture
    KR100539284B1|2005-12-28|Fiber-reactive disazo dyestuffs
    JPH06287460A|1994-10-11|1:2 chrome complex dye
    DE4130806A1|1993-03-18|UNBALANCED 1: 2 CHROME COMPLEX DYES
    US3532455A|1970-10-06|Method for producing sulfurized vat dyes by thionation and products thereof
    CN1210552A|1999-03-10|Fibre-reactive dyestuffs
    CA1045134A|1978-12-26|Anthraquinone compounds
    SU651711A3|1979-03-05|Method of obtaining asymmetric 1:2 chromium complexes of azo dyes
    CH639121A5|1983-10-31|Monoazo compounds having a fibre-reactive radical, preparation thereof and use thereof in dyeing and printing leather
    DE1904112A1|1971-08-12|Process for the production of fiber-reactive, heavy metal-containing formazan dyes
    DE1928542C|1972-06-08|Brown reactive dyes and their uses
    DE2608535A1|1976-09-16|NEW CHROME COMPLEX DYES, THEIR PRODUCTION AND USE
    GB2055117A|1981-02-25|Improvement in or relating to organic compounds
    EP0219741A2|1987-04-29|Mixtures and preparations of reactive dyes soluble in water
    DE2824211A1|1979-12-06|Prepn. of soluble fibre-reactive phthalocyanine dyes - using pyridine sulphonic or carboxylic acid as catalyst
    DE2429524C2|1986-07-24|Chromium-containing azo dyes, their production and use
    US4217270A|1980-08-12|Sulfo substituted chromium containing azo pyrazolone dyestuff
    CN109370255A|2019-02-22|A kind of dark color reactive dye compound and dye preparations
    CH664764A5|1988-03-31|New 1:2 chromium complex sulphonated dis:azo dyestuff cpds.
    KR0131760B1|1998-04-13|Phthalocyanine compound, rrocess for dyeing or printing of organic substructure by using the smae
    同族专利:
    公开号 | 公开日
    ES8200135A1|1981-10-16|
    IT1128567B|1986-05-28|
    AU541681B2|1985-01-17|
    FR2465768B1|1984-11-09|
    JPS6123948B2|1986-06-09|
    ES495246A0|1981-10-16|
    CH649773A5|1985-06-14|
    DE3034576C2|1987-04-09|
    BR8006083A|1981-04-07|
    US4396544A|1983-08-02|
    AU6258380A|1981-04-09|
    FR2465768A1|1981-03-27|
    GB2059431B|1983-05-25|
    GB2059431A|1981-04-23|
    DE3034576A1|1981-04-09|
    JPS5655457A|1981-05-16|
    HK59786A|1986-08-22|
    IT8049724D0|1980-09-23|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US2906746A|1959-09-29|Metalliferous azo dyestuffs |
    US3005813A|1953-05-22|1961-10-24|Ciba Ltd|Metalliferous azo-dyestuffs|
    DE1012007B|1953-06-08|1957-07-11|Ciba Geigy|Process for the production of chromium-containing azo dyes|
    US2806760A|1953-06-10|1957-09-17|Ciba Ltd|Process for dyeing nitrogenous fibers with metalliferous monoazo dyestuffs|
    DE1262478B|1961-12-21|1968-03-07|Wolfen Filmfab Veb|Process for the production of a chromium-containing mixed complex dye from monoazo dyes|
    CH427095A|1965-10-01|1966-12-31|Sandoz Ag|Process for the preparation of mixed complex compounds|
    GB1163713A|1966-02-10|1969-09-10|Ici Ltd|Chromium-Containing Azo Dyestuffs|
    CH499585A|1967-03-08|1970-11-30|Sandoz Ag|Process for the preparation of monoazo dyes and their metal complexes|
    US4159983A|1975-07-25|1979-07-03|Sandoz Ltd.|Pure and substantially pure asymmetric 1:2 cobalt complexes of monoazo compounds|
    CH616444A5|1975-07-25|1980-03-31|Sandoz Ag|Process for the preparation of asymmetric 1:2 cobalt complex azo compounds|US4502860A|1982-07-02|1985-03-05|Ciba-Geigy Corporation|Bis-1:2-chromium complexes of disazo dyes, and their preparation and use|
    CH658065A5|1984-03-08|1986-10-15|Ciba Geigy Ag|METHOD FOR PRODUCING 1: 2 CHROME COMPLEX DYES.|
    CH658252A5|1984-03-08|1986-10-31|Ciba Geigy Ag|METHOD FOR PRODUCING 1: 2 CHROME COMPLEX DYES.|
    CH664763A5|1985-01-24|1988-03-31|Ciba Geigy Ag|UNBALANCED CHROME COMPLEX DYES.|
    CH688281A5|1987-12-04|1997-07-15|Ciba Geigy Ag|A process for producing 1: 2-Metallkomplexazofarbstoffen.|
    EP1361074B1|2002-04-26|2005-06-29|OKT Kunststofftechnik GmbH|Method for improving the metallic appearance, the processability and the flexibility of resin coated decorative paper|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    CH8600/79A|CH649773A5|1979-09-24|1979-09-24|ASYMMETRIC 1: 2 CHROMIUM COMPLEX AROMATIC azo compounds, METHOD FOR THE PRODUCTION AND CONTAINING preparations.|
    [返回顶部]